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Structure and spectroscopy of CuH prepared via borohydride reduction

Bennett, E.L. and Wilson, T. and Murphy, P.J. and Refson, K. and Hannon, A.C. and Imberti, S. and Callear, S.K. and Chass, G.A. and Parker, S.F. (2015) Structure and spectroscopy of CuH prepared via borohydride reduction. Acta Crystallographica Section B, 7 (6). pp. 608-612. DOI: 10.1107/S2052520615015176

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Abstract

Copper(I) hydride (cuprous hydride, CuH) was the first binary metal hydride to be discovered (in 1844) and is singular in that it is synthesized in solution, at ambient temperature. There are several synthetic paths to CuH, one of which involves reduction of an aqueous solution of CuSO4·5H2O by borohydride ions. The product from this procedure has not been extensively characterized. Using a combination of diffraction methods (X-ray and neutron) and inelastic neutron scattering spectroscopy, we show that the CuH from the borohydride route has the same bulk structure as CuH produced by other routes. Our work shows that the product consists of a core of CuH with a shell of water and that this may be largely replaced by ethanol. This offers the possibility of modifying the properties of CuH produced by aqueous routes.

Item Type: Article
Subjects: Research Publications
Departments: College of Physical and Applied Sciences > School of Chemistry
Date Deposited: 08 Dec 2015 03:36
Last Modified: 18 Dec 2015 03:49
ISSN: 2052-5206
URI: http://e.bangor.ac.uk/id/eprint/5930
Identification Number: DOI: 10.1107/S2052520615015176
Publisher: Wiley
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