How the Surface Structure Determines the Properties of CuH

Bennett, E. and Wilson, T. and Murphy, P.J. and Refson, K. and Hannon, A.C. and Imberti, S. and Callear, S.K. and Chass, G.A. and Parker, S.F. (2015) How the Surface Structure Determines the Properties of CuH. Inorganic Chemistry, 54 (5). pp. 2213-2220. DOI: 10.1021/ic5027009

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CuH occurs in fields ranging from catalysis to electrochemistry to organic synthesis. We show that, while both aqueous and nonaqueous methods for the synthesis of CuH result in the same bulk product, the surface properties differ: bonded hydroxyls from aqueous routes and a coordinated donor from nonaqueous routes. This work provides a particularly clear example of how the nature of an adsorbed layer on a nanoparticle surface determines the properties

Item Type: Article
Subjects: Research Publications
Departments: College of Physical and Applied Sciences > School of Chemistry
Date Deposited: 22 May 2015 02:47
Last Modified: 23 Sep 2015 02:49
ISSN: 0020-1669
URI: http://e.bangor.ac.uk/id/eprint/4580
Identification Number: DOI: 10.1021/ic5027009
Publisher: American Chemical Society
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