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Characterization of the Hydrides in Stryker’s Reagent: [HCu{P(C6H5)3}]6

Bennett, E.L. and Murphy, P.J. and Imberti, S. Parker S.F. (2014) Characterization of the Hydrides in Stryker’s Reagent: [HCu{P(C6H5)3}]6. Inorganic Chemistry, 53 ((6)). pp. 2963-2967. DOI: 10.1021/ic402736t

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Abstract

A structural, spectroscopic, and computational investigation of Stryker�s reagent, [HCu{P(C6H5)3}]6, and its isotopomers has provided new insights into the complex. Neutron diffraction shows that the hydrides are best described as edge bridging rather than face bridging. The combination of infrared, inelastic neutron scattering spectroscopies and ab initio studies has allowed the location of most of the modes associated with the hydrides and their assignments.

Item Type: Article
Subjects: Research Publications
Departments: College of Physical and Applied Sciences > School of Chemistry
Date Deposited: 09 Dec 2014 16:33
Last Modified: 23 Sep 2015 02:59
ISSN: 0020-1669
URI: http://e.bangor.ac.uk/id/eprint/444
Identification Number: DOI: 10.1021/ic402736t
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