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A New Decaoxidooctaborate(2-) Anion, [B8O10(OH)(6)}(2-): Synthesis and Characterization of [Co(en)3][B5O6(OH)(4)][B8O10(OH)(6))]center dot 5H(2)O (en=1,2-Diaminoethane)

Altahan, M.A. and Beckett, M.A. and Coles, S.J. and Horton, P.N. (2014) A New Decaoxidooctaborate(2-) Anion, [B8O10(OH)(6)}(2-): Synthesis and Characterization of [Co(en)3][B5O6(OH)(4)][B8O10(OH)(6))]center dot 5H(2)O (en=1,2-Diaminoethane). Inorganic Chemistry, 54 (2). pp. 412-414. DOI: 10.1021/ic5027834

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Abstract

The synthesis and XRD structure of [Co(en)3][B5O6(OH)4][B8O10(OH)6].5H2O (1) is reported. Compound 1 arises through a selective templating process from a DCL of polyborate anions. Compound 1 contains two different polyborate species with [B8O10(OH)6]2- being particularly novel. It is comprised of a fused tetraborate and pentaborate anions with a 4-coordinate B atom and a 3 coordinate O atom in common.

Item Type: Article
Subjects: Research Publications
Departments: College of Physical and Applied Sciences > School of Chemistry
Date Deposited: 24 Mar 2015 03:31
Last Modified: 08 Jan 2016 03:23
ISSN: 0020-1669
URI: http://e.bangor.ac.uk/id/eprint/3676
Identification Number: DOI: 10.1021/ic5027834
Publisher: American Chemical Society
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