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Preparation of an ABC tricyclic model of the cylindrospermopsin alkaloids via a biomimetically inspired pathway

Evans, D.M. and Horton, P.N. and Hursthouse, M.B. Murphy P.J. (2014) Preparation of an ABC tricyclic model of the cylindrospermopsin alkaloids via a biomimetically inspired pathway. RSC Advances, 4 ((40)). pp. 20744-20751. DOI: 10.1039/C4RA03031A

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Abstract

Two tricyclic guanidine model compounds 28 and 29 have been prepared in 12 steps from 1,5-pentanediol using a biomimetic synthetic approach. The pivotal reaction in the sequence is a tethered Biginelli condensation between 21/22 and β-keto esters 23 and 24.

Item Type: Article
Subjects: Research Publications
Departments: College of Physical and Applied Sciences > School of Chemistry
Date Deposited: 09 Dec 2014 16:31
Last Modified: 23 Sep 2015 02:58
ISSN: 2046-2069
URI: http://e.bangor.ac.uk/id/eprint/351
Identification Number: DOI: 10.1039/C4RA03031A
Publisher: Royal Society of Chemistry
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